Nanostructured PbS-doped inorganic film synthesized by sol-gel route

IV-VI semiconductor quantum dots embedded into an inorganic matrix represent nanostructured composite materials with potential application in temperature sensor systems. This study explores the optical, structural, and morphological properties of a novel PbS quantum dots (QDs)- doped inorganic thin film belonging to the Al2O3 -SiO2 -P2O5 system. The film was synthesized by the sol-gel method, spin coating technique, starting from a precursor solution deposited on a glass substrate in a multilayer process, followed by drying of each deposited layer. Crystalline PbS QDs embedded in the inorganic vitreous host matrix formed a nanocomposite material. Specific investigations such as X-ray diffraction (XRD), optical absorbance in the ultraviolet (UV)-visible (Vis)-near infrared (NIR) domain, NIR luminescence, Raman spectroscopy, scanning electron microscopy– energy dispersive X-ray (SEM-EDX), and atomic force microscopy (AFM) were used to obtain a comprehensive characterization of the deposited film. The dimensions of the PbS nanocrystallite phase were corroborated by XRD, SEM-EDX, and AFM results. The luminescence band from 1400 nm follows the luminescence peak of the precursor solution and that of the dopant solution. The emission of the PbS-doped film in the NIR domain is a premise for potential application in temperature sensing systems.This study was funded by a grant of the Romanian National Authority for Scientific Research and Innovation, CCCDI–UEFISCDI, project ERANET-MANUNET-TEMSENSOPT, MNET20/ NMCS3732, within PNCDI III, contract 213/02.12.2020; Ministry of Research, Innovation and Digitalization (MRID), Core Program, contracts no. 16N/2019, 18N/2019 and 21N/2019; MRID through Program I—Development of the National R & D System, Subprogram 1.2–Institutional Performance– Projects for Excellence Financing in RDI, contracts no. 13PFE/2021, 18PFE/2021 and 35PFE/2021; CCCDI-UEFISCDI project PN-III-P2-2.1-PED-2021-2541. Support from the Public University of Navarre for Research Groups is also acknowledged

SIP-AIP conversion component: Reference Implementation

This report is about the E-ARK AIP format specification. There is a common structure of information packages shared between the different types of information packages which is defined by the document “Common Specification for Information Packages”. The current report references this Common Specification and focuses on the structural peculiarities of the AIP format and the implementation as part of the reference implementation E-ARK Web (in short: earkweb). Key objectives of this document are: To define a generic structure of the AIP format in a way that it is suitable for a wide variety of data types, such as document and image collections, archival records, databases or geographical data. To recommend a set of metadata related to the structural and the preservation aspects of the AIP as implemented by the reference implementation (earkweb). To ensure the format is also suitable to store large quantities of data

E‐ARK Search, Access and Display Interfaces

The aim of this report is to describe the “Search, Access and Display Interfaces” that have been developed in the Access component of the E-ARK project. The deliverable associated with this report is mainly a software deliverable and therefore this document provides only underpinning descriptions of and links to the software itself. The tools that are described and provided allow Consumers (ie. end-users and archivists) to: 1. Search and order records (primarily end-users, but also archivists) 2. Manage orders of records and manage the records themselves, including the AIP to DIP conversion (archivists only) 3. Access ordered records as DIPs (primarily end-users, but also archivists) In addition to the the introductory remarks in chapter 2, the functionality of the tools that allow the Consumers to search, manage, and access records is described in chapter 3. After the description of each tool, links are provided to code and documentation

An OAIS-oriented System for Fast Package Creation, Search, and Access: Paper - iPRES 2016 - Swiss National Library, Bern

This paper describes the scalable e-archiving repository system developed in the context of the E-ARK project. The system is built using a stack of widely used technologies that are known from areas such as search engine development, information retrieval and data-intensive computing, enabling efficient storage and processing of large volumes of data. The E-ARK Integrated Platform Reference Implementation Prototype takes advantage of these technologies and implements an OAIS-oriented repository system for creating, archiving, and accessing data as information packages. The system consists of software components including an efficient file handling infrastructure, a configurable and scalable ingest system, a powerful full-text-based search server, and a distributed repository providing file-level random access. This paper gives an overview of the architecture and technical components that have been used to build the prototype. Furthermore, the paper provides experimental results and gives directions for future work

Nanostructured PbS-Doped Inorganic Film Synthesized by Sol-Gel Route

IV-VI semiconductor quantum dots embedded into an inorganic matrix represent nanostructured composite materials with potential application in temperature sensor systems. This study explores the optical, structural, and morphological properties of a novel PbS quantum dots (QDs)-doped inorganic thin film belonging to the Al2O3-SiO2-P2O5 system. The film was synthesized by the sol-gel method, spin coating technique, starting from a precursor solution deposited on a glass substrate in a multilayer process, followed by drying of each deposited layer. Crystalline PbS QDs embedded in the inorganic vitreous host matrix formed a nanocomposite material. Specific investigations such as X-ray diffraction (XRD), optical absorbance in the ultraviolet (UV)-visible (Vis)-near infrared (NIR) domain, NIR luminescence, Raman spectroscopy, scanning electron microscopy–energy dispersive X-ray (SEM-EDX), and atomic force microscopy (AFM) were used to obtain a comprehensive characterization of the deposited film. The dimensions of the PbS nanocrystallite phase were corroborated by XRD, SEM-EDX, and AFM results. The luminescence band from 1400 nm follows the luminescence peak of the precursor solution and that of the dopant solution. The emission of the PbS-doped film in the NIR domain is a premise for potential application in temperature sensing systems

A Nanocomposite Sol-Gel Film Based on PbS Quantum Dots Embedded into an Amorphous Host Inorganic Matrix

In this study, a sol-gel film based on lead sulfide (PbS) quantum dots incorporated into a host network was synthesized as a special nanostructured composite material with potential applications in temperature sensor systems. This work dealt with the optical, structural, and morphological properties of a representative PbS quantum dot (QD)-containing thin film belonging to the Al2O3–SiO2–P2O5 system. The film was prepared using the sol-gel method combined with the spin coating technique, starting from a precursor solution containing a suspension of PbS QDs in toluene with a narrow size distribution and coated on a glass substrate in a multilayer process, followed by annealing of each deposited layer. The size (approximately 10 nm) of the lead sulfide nanocrystallites was validated by XRD and by the quantum confinement effect based on the band gap value and by TEM results. The photoluminescence peak of 1505 nm was very close to that of the precursor PbS QD solution, which demonstrated that the synthesis route of the film preserved the optical emission characteristic of the PbS QDs. The photoluminescence of the lead sulfide QD-containing film in the near infrared domain demonstrates that this material is a promising candidate for future sensing applications in temperature monitoring

A New Zinc Phosphate-Tellurite Glass for Magneto-Optical Applications

This work investigates the structural, magnetic and magneto-optical properties of a new zinc phosphate-tellurite glass belonging to the 45ZnO-10Al2O3-40P2O5-5TeO2 system. The glass was prepared by a wet method of processing the starting reagents followed by suitable melting–stirring–quenching–annealing steps. Specific parameters such as density, average molecular mass, molar volume, oxygen packaging density, refractive index, molar refractivity, electronic polarizability, reflection loss, optical transmission, band gap and optical basicity have been reported together with thermal, magnetic and magneto-optical characteristics. Absorption bands appear in the blue and red visible region, while over 600 nm the glass becomes more transparent. FTIR and Raman spectra evidenced phosphate-tellurite vibration modes proving the P2O5 and TeO2 network forming role. Magnetic measurements reveal the diamagnetic character of the Te-doped glass with an additional weak ferromagnetic signal, specific to diluted ferromagnetic oxides. Positive Faraday rotation angle with monotonous decreasing value at increasing wavelength was evidenced from magneto-optical measurements. The final product is a composite material comprising of a non-crystalline vitreous phase and Te-based nanoclusters accompanied by oxygen vacancies. The metallic-like Te colloids are responsible for the dark reddish color of the glass whereas the accompanying oxygen vacancies might be responsible for the weak ferromagnetic signal persisting up to room temperature